9,740 research outputs found
A Balancing-Process Approach to Firm Internationalization
Drawing on the resource-based view of the firm, this paper develops a balancing-process approach to explain the motivations and location choices of foreign direct investment (FDI). In this approach, FDI is viewed as a means to balance a firm's portfolio of resources and capabilities through utilizing foreign strategic factor markets with the ultimate goal of achieving growth and sustainable competitive advantage. This approach joins exploitative and explorative FDI in a single framework and helps explain why a firm can conduct both types of FDI simultaneously.
A Novel Euler's Elastica based Segmentation Approach for Noisy Images via using the Progressive Hedging Algorithm
Euler's Elastica based unsupervised segmentation models have strong
capability of completing the missing boundaries for existing objects in a clean
image, but they are not working well for noisy images. This paper aims to
establish a Euler's Elastica based approach that properly deals with random
noises to improve the segmentation performance for noisy images. We solve the
corresponding optimization problem via using the progressive hedging algorithm
(PHA) with a step length suggested by the alternating direction method of
multipliers (ADMM). Technically, all the simplified convex versions of the
subproblems derived from the major framework of PHA can be obtained by using
the curvature weighted approach and the convex relaxation method. Then an
alternating optimization strategy is applied with the merits of using some
powerful accelerating techniques including the fast Fourier transform (FFT) and
generalized soft threshold formulas. Extensive experiments have been conducted
on both synthetic and real images, which validated some significant gains of
the proposed segmentation models and demonstrated the advantages of the
developed algorithm
ACCESS CONTROL USING WIRELESS FOR DATA COMMUNICATATION TO DATA TERMINAL
The main objective of this project is to develop wireless
access control that can be accessed via HTML website using Microchip development board. TCP/IP protocol is used for its wireless technology, using ZeroG module that provides 802.11 standards. Application of wireless access control starts with initialization of hardware and computer through IP address assigned by access point
Multicomponent Diels-Alder Sequences of 1-Aminodendralenes
This thesis explores the use of in situ generated acyclic
1-aminodendralenes in multicomponent diene-transmissive
Diels-Alder (DTDA) reaction sequences. Dendralenes have
previously been shown to generate polycyclic frameworks in a
step-economic manner. The 1-amino substituent is shown to promote
very high levels of site selectivity in these processes.
Chapter 1 reviews the Diels-Alder reactions of
1-amino-1,3-butadienes and is divided
into three sections. The first two sections cover the Diels-Alder
reactions of
1-amino-1,3-butadienes and 1-amino-3-siloxy-1,3-butadienes
(Rawal’s dienes)
generated with a stoichiometric amount of amine. The third
section covers
enantioselective Diels-Alder reactions involving
1-amino-1,3-butadienes generated in
situ with a catalytic amount of a chiral amine. While there have
been many reports of
Diels-Alder reactions of 1-amino-1,3-butadienes and
1-amino-3-siloxy-1,3-butadienes,
there has been only one involving a semi-cyclic
1-amino[3]dendralene. There have been
few examples which combine these Diels-Alder reactions with other
transformations in
multicomponent reactions to generate polycyclic frameworks.
Chapter 2 describes the use of acyclic 1-amino[3]dendralenes in
multicomponent
reactions to generate a diverse range of heterocyclic structures.
The condensation/Diels-
Alder reaction sequence was tolerant of a variety of amines as
well as carbon and
hereoatom-based dienophiles. The Diels-Alder reactions of
1-amino[3]dendralenes were
highly site-selective, taking place exclusively at the amine
substituted 1,3-butadiene
unit. The sequence was extended to a one-pot four-component
reaction by including an
additional dienophile for a Diels-Alder reaction to take place at
the newly generated
semi-cyclic diene. These condensation/Diels-Alder/Diels-Alder
cycloadducts were
generated with high diastereoselectivity, the origins of which
were investigated and
explained with the use of density functional theory calculations
(carried out by Prof
Paddon-Row). By reversing the order of events, that is performing
a Diels-Alder
reaction on the skipped dienal precursor before the
condensation/Diels-Alder reaction
sequence, constitutional isomers were accessed. The second
Diels-Alder reaction could be performed intramolecularly when an
amine bearing an alkenyl substituent was used. This
condensation/Diels-Alder/intramolecular Diels-Alder reaction
sequence furnished a variety of tricyclic and tetracyclic
heterocycles.
Chapter 3 describes the use of acyclic 1-aminodendralenes bearing
chiral amines in
organocatalytic, enantioselective Diels-Alder reactions to
deliver enantioenriched
cycloadducts. The enantioselective Diels-Alder reaction between
1-amino[3]dendralenes, the condensation product of skipped
dienals and chiral amines,
and various dienophiles followed by elimination of the amine
generated trienal
cycloadducts in good yield and high enantioselectivity. The
reaction tolerates
substitution on the skipped dienal as well as dienophiles
possessing an aldehyde
substituent at the α position. Extension of this methodology by
performing Wittig and Diels-Alder reactions on the trienal
cycloadducts enabled access to enantioenriched polycyclic
products. By using a diene-dialdehyde as the starting precursor,
it is anticipated that the Horeau principle would operate in the
twofold condensation/Diels-Alder/elimination reaction sequence
would furnish the cycloadduct in high enantioselectivity. A
preliminary attempt successfully generated the desired
cycloadduct as the major product
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